Issue 52, 2020
From the journal:

Chemical Communications

ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping†

Egor A. Ilin,ab   Vladimir O. Smirnov, ORCID logo a   Alexander D. Volodin, ORCID logo c   Alexander A. Korlyukov ORCID logo c  and  Alexander D. Dilman ORCID logo *a  

* Corresponding authors

a N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation

b Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, 119991 Moscow, Russian Federation

c A. N. Nesmeyanov Institute of Organoelement Compounds, Vavilov str. 28, 119991 Moscow, Russian Federation

Abstract

Compounds bearing ortho-oriented dialkylamino and boryl groups can serve as efficient reagents to trap difluorocarbene leading to zwitterionic ammonium borates featuring N-CF2-B fragments. The reagents are shelf-stable and can be used as mechanistic probes for reactions proceeding via difluorocarbene.

Graphical abstract: ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping

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Article information

DOI
https://doi.org/10.1039/D0CC02567D
Article type
Communication
Submitted
09 Apr 2020
Accepted
20 May 2020
First published
20 May 2020

Chem. Commun., 2020,56, 7140-7142

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ortho-Dialkylamino arylboranes as efficient reagents for difluorocarbene trapping

E. A. Ilin, V. O. Smirnov, A. D. Volodin, A. A. Korlyukov and A. D. Dilman, Chem. Commun., 2020, 56, 7140 DOI: 10.1039/D0CC02567D

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