Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 26, 2020
Previous Article Next Article

Unlocking the direct photocatalytic difluoromethylation of C[double bond, length as m-dash]N bonds

Author affiliations

Abstract

The current study presents a direct CF2H radical addition to C[double bond, length as m-dash]N bonds predicated on the photocatalytic activation of commercially available zinc difluoromethanesulfinate. The mild conditions in place lead to impressive structural diversity, as quinoxalinones and dibenzazepines, among others, are successfully functionalized.

Graphical abstract: Unlocking the direct photocatalytic difluoromethylation of C [[double bond, length as m-dash]] N bonds

Back to tab navigation

Supplementary files

Article information


Submitted
30 Jan 2020
Accepted
27 Feb 2020
First published
27 Feb 2020

This article is Open Access

Chem. Commun., 2020,56, 3769-3772
Article type
Communication

Unlocking the direct photocatalytic difluoromethylation of C[double bond, length as m-dash]N bonds

A. F. Garrido-Castro, A. Gini, M. C. Maestro and J. Alemán, Chem. Commun., 2020, 56, 3769
DOI: 10.1039/D0CC01353F

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements