Acridine orange as a coreactant for efficient electrogenerated chemiluminescence of tris(2,2′-bipyridine)ruthenium(ii) and its use in selective and sensitive detection of thiourea

Abstract

A new and efficient anodic Ru(bpy)₃²⁺ ECL system by using acridine orange (3,6-Bis(dimethylamino)acridine, AO) as a coreactant was reported in a neutral medium. The developed Ru(bpy)₃²⁺–AO system displayed a higher ECL intensity than that of the classic Ru(bpy)₃²⁺– oxalate ECL system, and was further exploited for the ECL detection of thiourea for the first time.