Issue 26, 2020

A micro-environment tuning approach for enhancing the catalytic capabilities of lanthanide containing polyoxometalate in the cyanosilylation of ketones

Abstract

The as-synthesized (TBA)8H5[Nd(SiW11O39)2] manifested high catalytic activity for cyanosilylation of ketones, and its catalytic activity could be improved further through rational design of the reaction micro-environment beyond the molecular level, and the corresponding mechanism has been systematically studied.

Graphical abstract: A micro-environment tuning approach for enhancing the catalytic capabilities of lanthanide containing polyoxometalate in the cyanosilylation of ketones

Supplementary files

Article information

Article type
Communication
Submitted
15 Feb 2020
Accepted
25 Feb 2020
First published
26 Feb 2020

Chem. Commun., 2020,56, 3809-3812

A micro-environment tuning approach for enhancing the catalytic capabilities of lanthanide containing polyoxometalate in the cyanosilylation of ketones

Y. Nie, S. Li, M. Lin and J. Yan, Chem. Commun., 2020, 56, 3809 DOI: 10.1039/D0CC01216E

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