Issue 28, 2020
From the journal:

Chemical Communications

A supersalt-type copper(i)-thiolate cluster with applications for mechano/thermochromism and the oxygen evolution reaction†

Lanxia Hu,‡a   Aiping Zheng,‡a   Yao Kang,*a   Tian Wen ORCID logo *a  and  Jian Zhang ORCID logo a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: ky@fjirsm.ac.cn, twen@fjirsm.ac.cn

Abstract

A new copper(I)–thiolate (Cu–S) cluster with a CsCl unit (1, [Cu12(μ4-SCH3)6(NH3)12][Cu12(μ4-SCH3)6Cl12]) exhibited interesting mechanochromic and thermochromic luminescence properties. Additionally, heteroatom-rich 1 could also be used as an electrocatalyst for the oxygen evolution reaction in alkaline media. The supersalt-type Cu–S cluster for the first time realized mechano/thermochromic and electrocatalytic applications.

Graphical abstract: A supersalt-type copper(i)-thiolate cluster with applications for mechano/thermochromism and the oxygen evolution reaction

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Article information

DOI
https://doi.org/10.1039/D0CC00619J
Article type
Communication
Submitted
22 Jan 2020
Accepted
24 Feb 2020
First published
25 Feb 2020

Chem. Commun., 2020,56, 3967-3970

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A supersalt-type copper(I)-thiolate cluster with applications for mechano/thermochromism and the oxygen evolution reaction

L. Hu, A. Zheng, Y. Kang, T. Wen and J. Zhang, Chem. Commun., 2020, 56, 3967 DOI: 10.1039/D0CC00619J

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