Issue 24, 2020

Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes

Abstract

Isosmaragdyrin with an N3C2 core is successfully achieved by introducing a 2,6-di-m-phenylpyridine unit. The core is utilized to stabilize the Rh(I) ion in the N–Rh(I)–N bonding mode and the Pt(II) ion in the (N^C)N fashion to form an unsymmetrical pincer-type organometallic complex.

Graphical abstract: Isosmaragdyrin with an N3C2 core: stabilization of Rh(i) and organo-Pt(ii) complexes

Supplementary files

Article information

Article type
Communication
Submitted
09 Jan 2020
Accepted
17 Feb 2020
First published
18 Feb 2020

Chem. Commun., 2020,56, 3551-3554

Isosmaragdyrin with an N3C2 core: stabilization of Rh(I) and organo-Pt(II) complexes

M. Das, S. Chitranshi, M. Murugavel, B. Adinarayana, C. H. Suresh and A. Srinivasan, Chem. Commun., 2020, 56, 3551 DOI: 10.1039/D0CC00214C

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