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Issue 18, 2020
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Gold and hypervalent iodine(iii): liaisons over a decade for electrophilic functional group transfer reactions

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Abstract

Over the last two decades, hypervalent iodine(III) reagents have evolved from being ‘bonding curiosities’ to mainstream reagents in organic synthesis, in particular, electrophilic functional group transfer reactions. In this context, gold catalysts have not only emerged as a unique toolbox to facilitate such reactions (especially alkynylations) but also opened new possibilities with their different modes of reactivities for other functional group transfer reactions (acetoxylations and arylations). This feature article critically summarizes hitherto all such Au-catalyzed electrophilic functional group transfer reactions with hypervalent iodine(III) reagents, emphasizing their mechanistic aspects.

Graphical abstract: Gold and hypervalent iodine(iii): liaisons over a decade for electrophilic functional group transfer reactions

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Article information


Submitted
06 Jan 2020
Accepted
06 Feb 2020
First published
06 Feb 2020

Chem. Commun., 2020,56, 2677-2690
Article type
Feature Article

Gold and hypervalent iodine(III): liaisons over a decade for electrophilic functional group transfer reactions

S. Banerjee, V. W. Bhoyare and N. T. Patil, Chem. Commun., 2020, 56, 2677
DOI: 10.1039/D0CC00106F

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