Issue 27, 2020

A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function

Abstract

Although the chemistry of frustrated Lewis pairs (FLPs) has seen tremendous developments, investigations on anionic, mono-molecular FLPs are still scarce and 1,3-zwitterions are unknown. Herein, synthesis of a K/OR phosphinidenoid complex bearing a Si–Cl function is reported and, hence, can serve as a synthetic equivalent for a 1,3-zwitterion to allow access to rare and novel heterocyclic P-ligands.

Graphical abstract: A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function

Supplementary files

Article information

Article type
Communication
Submitted
02 Jan 2020
Accepted
26 Feb 2020
First published
06 Mar 2020

Chem. Commun., 2020,56, 3899-3902

A synthetic equivalent for unknown 1,3-zwitterions? – A K/OR phosphinidenoid complex with an additional Si–Cl function

R. Kunzmann, Y. Omatsu, G. Schnakenburg, A. Espinosa Ferao, T. Yanagisawa, N. Tokitoh and R. Streubel, Chem. Commun., 2020, 56, 3899 DOI: 10.1039/D0CC00024H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements