A copper-catalyzed borylative amidation of vinyl arenes with isocyanates and bis(pinacolato)diboron has been developed. This new protocol, which can be performed on a gram-scale, utilizes isocyanates as simple precursors to provide access to a range of boryl alkyl amides. The products contain valuable amide and boronate, which are amenable for further elaboration, and have versatile synthetic utilities.
Z. Su, Y. Feng, R. Zou, X. Qiu, J. Wang and C. Tao, Chem. Commun., 2020, 56, 7483 DOI: 10.1039/C9CC09902F
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