Palladium-catalyzed cascade reactions of enynones and isocyanides: access towards functionalized ketenimine and its application

Jie Huang; Feng Li; Lei Cui; Shikuan Su; Xueshun Jia; Jian Li

doi:10.1039/C9CC09363J

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Palladium-catalyzed cascade reactions of enynones and isocyanides: access towards functionalized ketenimine and its application†

Jie Huang,^a Feng Li,^a Lei Cui,*^a Shikuan Su,^a Xueshun Jia*^ab and Jian Li

*^a

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* Corresponding authors

^a Department of Chemistry, College of Sciences & Institute for Sustainable Energy, Shanghai University, 99 Shangda Road, Shanghai 200444, P. R. China
E-mail: cuilei@shu.edu.cn, xsjia@mail.shu.edu.cn, lijian@shu.edu.cn

^b State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China

Abstract

Palladium-catalyzed cascade reactions of enynones and isocyanides have been disclosed. This strategy allows for the synthesis of structurally unusual furan-incorporated ketenimines, which are stable and can undergo a formal [4+1] annulation with another isocyanide to yield indenone derivatives.

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DOI: https://doi.org/10.1039/C9CC09363J
Article type: Communication
Submitted: 02 Dec 2019
Accepted: 13 Mar 2020
First published: 13 Mar 2020

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Chem. Commun., 2020,56, 4555-4558

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Palladium-catalyzed cascade reactions of enynones and isocyanides: access towards functionalized ketenimine and its application

J. Huang, F. Li, L. Cui, S. Su, X. Jia and J. Li, Chem. Commun., 2020, 56, 4555 DOI: 10.1039/C9CC09363J

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Chemical Communications

Palladium-catalyzed cascade reactions of enynones and isocyanides: access towards functionalized ketenimine and its application†

Abstract

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Palladium-catalyzed cascade reactions of enynones and isocyanides: access towards functionalized ketenimine and its application

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