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Issue 1, 2020
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A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

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Abstract

An atypical homochiral spin-crossover (SCO) framework (1) constructed from mechanically interlocked 1D molecular loops was prepared. Due to the flexibility of the interlocked structure, the guest solvent molecules can be reversibly exchanged. Consequently, its SCO behavior was capable of modulating between one- and two-stepped transitions in response to acetonitrile and methanol.

Graphical abstract: A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

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Article information


Submitted
21 Nov 2019
Accepted
26 Nov 2019
First published
26 Nov 2019

Chem. Commun., 2020,56, 133-136
Article type
Communication

A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin-state switching behaviors

X. Sun, Z. Tang, Z. Yao and J. Tao, Chem. Commun., 2020, 56, 133
DOI: 10.1039/C9CC09063K

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