Issue 1, 2020

Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates

Abstract

The iodofluorination of alkynyl and alkenyl MIDA (N-methyliminodiacetyl) boronates led to the synthesis of two types of fluorinated organoborons bearing a valuable C–I bond. The B(MIDA) moiety confers exclusive regioselectivity to the reaction, and the products were formed in generally good yields. Preliminary utility of the products was demonstrated.

Graphical abstract: Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates

Supplementary files

Article information

Article type
Communication
Submitted
26 Oct 2019
Accepted
25 Nov 2019
First published
26 Nov 2019

Chem. Commun., 2020,56, 82-85

Synthesis of fluorinated amphoteric organoborons via iodofluorination of alkynyl and alkenyl MIDA boronates

W. Fan, J. Li, W. Lv, L. Yang, Q. Li and H. Wang, Chem. Commun., 2020, 56, 82 DOI: 10.1039/C9CC08386C

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