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Issue 3, 2020
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Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

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Abstract

Two pentadentate N3,P2 ligands coordinate zinc(II) by their N3 pocket. Four free phosphine donors allow the coordination of four AuCl moieties leading to a pentanuclear ZnAu4 complex. In contrast, the attempt to use the phosphines for chelating coordination of two Rh(CO)Cl units results in a well-organized rearrangement that ends up with the formation of a metallomacrocycle in high yields.

Graphical abstract: Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

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Article information


Submitted
01 Oct 2019
Accepted
25 Nov 2019
First published
26 Nov 2019

Chem. Commun., 2020,56, 368-371
Article type
Communication

Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

C. Groß, Y. Sun, T. Jost, T. Grimm, M. P. Klein, G. Niedner-Schatteburg, S. Becker and W. R. Thiel, Chem. Commun., 2020, 56, 368
DOI: 10.1039/C9CC07723E

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