Issue 98, 2019

A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core

Abstract

A highly symmetric, dicationic tetranuclear calcium hydride cluster with an adamantoid [Ca4H6]2+ core stabilized by the NNN macrocycle Me3TACN (1,4,7-trimethyl-1,4,7-triazacyclononane) was prepared. DFT calculations indicate delocalized bonding within the [Ca4H6]2+ fragment with d-orbital contribution.

Graphical abstract: A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core

Supplementary files

Article information

Article type
Communication
Submitted
01 Nov 2019
Accepted
19 Nov 2019
First published
19 Nov 2019

Chem. Commun., 2019,55, 14837-14839

A tetranuclear calcium hydride cluster with a highly symmetric [Ca4H6]2+ core

D. Schuhknecht, T. P. Spaniol, I. Douair, L. Maron and J. Okuda, Chem. Commun., 2019, 55, 14837 DOI: 10.1039/C9CC08540H

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