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Issue 98, 2019
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A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

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Abstract

The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.

Graphical abstract: A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

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Supplementary files

Article information


Submitted
15 Oct 2019
Accepted
15 Nov 2019
First published
15 Nov 2019

Chem. Commun., 2019,55, 14781-14784
Article type
Communication

A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

N. Huang, X. Zhang, Y. Xu, P. Liao and X. Chen, Chem. Commun., 2019, 55, 14781 DOI: 10.1039/C9CC08094E

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