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Issue 99, 2019
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Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction

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Abstract

The first nickel-catalyzed intramolecular hydroacylation/Suzuki cross coupling cascade of o-allylbenzaldehydes with a broad range of phenylboronic acid neopentyl glycol esters has been developed. This strategy shows high regioselectivity and step economy in the construction of two C–C bonds via aldehyde C–H bond activation, affording valuable indanones with high efficiency.

Graphical abstract: Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction

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Article information


Submitted
26 Sep 2019
Accepted
15 Nov 2019
First published
18 Nov 2019

Chem. Commun., 2019,55, 14984-14987
Article type
Communication

Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction

S. Lee, L. Guo and M. Rueping, Chem. Commun., 2019, 55, 14984
DOI: 10.1039/C9CC07558E

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