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Issue 86, 2019
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Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

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Abstract

The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

Graphical abstract: Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

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Article information


Submitted
10 Sep 2019
Accepted
03 Oct 2019
First published
03 Oct 2019

Chem. Commun., 2019,55, 12944-12947
Article type
Communication

Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

G. Magnabosco, A. M. M. Condorelli, R. Rosenberg, I. Polishchuk, B. Pokroy, D. Gebauer, H. Cölfen and G. Falini, Chem. Commun., 2019, 55, 12944
DOI: 10.1039/C9CC07087G

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