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Issue 86, 2019
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Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction

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Abstract

Variable temperature X-ray diffraction studies on two single crystals containing M3N@C80, i.e., Ho2LuN@C80·NiOEP·2(C6H6) and Lu3N@C80·NiOEP·2(C6H6), (NiOEP = Nickel octaethylporphyrin) unravelled the temperature dependent rotation of the M3N cluster and C80 cage on the static NiOEP molecule.

Graphical abstract: Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction

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Supplementary files

Article information


Submitted
16 Aug 2019
Accepted
07 Oct 2019
First published
07 Oct 2019

Chem. Commun., 2019,55, 13000-13003
Article type
Communication

Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction

F. Liu and L. Spree, Chem. Commun., 2019, 55, 13000
DOI: 10.1039/C9CC06363C

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