Jump to main content
Jump to site search

Issue 74, 2019
Previous Article Next Article

Hysteretic four-step spin-crossover in a 3D Hofmann-type metal–organic framework with aromatic guest

Author affiliations

Abstract

A new Hofmann-type metal–organic framework with bent pillar ligand, [Fe(dpoda){Ag(CN)2}2] (dpoda = 2,5-di-(pyridyl)-1,3,4-oxadiazole), was synthesized. Four-, two- and one-step spin-crossover (SCO) properties were obtained by using different sizes of aromatic guests. Most importantly, hysteretic four-step SCO behaviour with the sequence of LS ↔ HS0.25LS0.75 ↔ HS0.5LS0.5 ↔ HS0.67LS0.33 ↔ HS is observed for the first time.

Graphical abstract: Hysteretic four-step spin-crossover in a 3D Hofmann-type metal–organic framework with aromatic guest

Back to tab navigation

Supplementary files

Publication details

The article was received on 02 Aug 2019, accepted on 20 Aug 2019 and first published on 21 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC06017K
Chem. Commun., 2019,55, 11033-11036

  •   Request permissions

    Hysteretic four-step spin-crossover in a 3D Hofmann-type metal–organic framework with aromatic guest

    C. Zhang, K. Lian, G. Huang, S. Bala, Z. Ni and M. Tong, Chem. Commun., 2019, 55, 11033
    DOI: 10.1039/C9CC06017K

Search articles by author

Spotlight

Advertisements