Reversing C2H2–CO2 adsorption selectivity in an ultramicroporous metal–organic framework platform

Hui-Min Wen; Caijun Liao; Libo Li; Ling Yang; Jing Wang; Liang Huang; Bin Li; Banglin Chen; Jun Hu

doi:10.1039/C9CC05997K

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Reversing C₂H₂–CO₂ adsorption selectivity in an ultramicroporous metal–organic framework platform†

Hui-Min Wen,^a Caijun Liao,^a Libo Li,^bc Ling Yang,^c Jing Wang,

^a Liang Huang,

^a Bin Li,

*^d Banglin Chen

*^b and Jun Hu

*^a

Author affiliations

* Corresponding authors

^a College of Chemical Engineering, Zhejiang University of Technology, Zhejiang, P. R. China
E-mail: hjzjut@zjut.edu.cn

^b Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA
E-mail: banglin.chen@utsa.edu
Fax: +1-210-458-7428

^c College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, P. R. China

^d State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou, China
E-mail: bin.li@zju.edu.cn

Abstract

In this work, we show that precise control of the pore size and functionality in an ultramicroporous metal–organic framework platform can finely tune the adsorption selectivity between acetylene and carbon dioxide at will.

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Article information

DOI: https://doi.org/10.1039/C9CC05997K
Article type: Communication
Submitted: 01 Aug 2019
Accepted: 27 Aug 2019
First published: 27 Aug 2019

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Chem. Commun., 2019,55, 11354-11357

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Reversing C₂H₂–CO₂ adsorption selectivity in an ultramicroporous metal–organic framework platform

H. Wen, C. Liao, L. Li, L. Yang, J. Wang, L. Huang, B. Li, B. Chen and J. Hu, Chem. Commun., 2019, 55, 11354 DOI: 10.1039/C9CC05997K

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Chemical Communications