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Issue 71, 2019
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Direct C–H/C–H cross-coupling of benzimidates with heteroarenes to access biheteroaryl-2-carbonitriles

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Abstract

A Rh-catalyzed C–H/C–H oxidative cross-coupling reaction of benzimidates with heteroarenes is developed, yielding biheteroaryl-2-carbonitriles directly after in situ dealcoholization. This protocol features high atom- and step-economy, and a broad substrate scope with good functional group tolerance.

Graphical abstract: Direct C–H/C–H cross-coupling of benzimidates with heteroarenes to access biheteroaryl-2-carbonitriles

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Supplementary files

Article information


Submitted
10 Jul 2019
Accepted
08 Aug 2019
First published
09 Aug 2019

Chem. Commun., 2019,55, 10599-10602
Article type
Communication

Direct C–H/C–H cross-coupling of benzimidates with heteroarenes to access biheteroaryl-2-carbonitriles

Z. Wang, F. Wang, Z. Liu, S. He, X. Pu, Y. Yang and G. Gao, Chem. Commun., 2019, 55, 10599
DOI: 10.1039/C9CC05314J

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