Deciphering the influence of structural distortions on the uniaxial magnetic anisotropy of pentagonal bipyramidal Ni(II) complexes

Mamon Dey; Prashurya Pritam Mudoi; Anup Choudhury; Bipul Sarma; Nayanmoni Gogoi

doi:10.1039/C9CC05032A

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Deciphering the influence of structural distortions on the uniaxial magnetic anisotropy of pentagonal bipyramidal Ni(ii) complexes†

Mamon Dey,^a Prashurya Pritam Mudoi,^a Anup Choudhury,^a Bipul Sarma

^a and Nayanmoni Gogoi

*^a

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* Corresponding authors

^a Department of Chemical Sciences, Tezpur University, Napaam, Sonitpur, Assam, India
E-mail: ngogoi@tezu.ernet.in

Abstract

The effect of subtle structural distortions on single ion magnetic anisotropy of pentagonal bipyramidal Ni(II) complexes was probed by magnetization measurements and theoretical calculations. Reducing structural distortion on the equatorial pentagonal plane and employing strong field ligands on axial coordination sites dramatically enhance the uniaxial magnetic anisotropy in pentagonal bipyramidal Ni(II) complexes.

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DOI: https://doi.org/10.1039/C9CC05032A
Article type: Communication
Submitted: 01 Jul 2019
Accepted: 30 Aug 2019
First published: 30 Aug 2019

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Chem. Commun., 2019,55, 11547-11550

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Deciphering the influence of structural distortions on the uniaxial magnetic anisotropy of pentagonal bipyramidal Ni(II) complexes

M. Dey, P. P. Mudoi, A. Choudhury, B. Sarma and N. Gogoi, Chem. Commun., 2019, 55, 11547 DOI: 10.1039/C9CC05032A

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Chemical Communications

Deciphering the influence of structural distortions on the uniaxial magnetic anisotropy of pentagonal bipyramidal Ni(ii) complexes†

Abstract

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Deciphering the influence of structural distortions on the uniaxial magnetic anisotropy of pentagonal bipyramidal Ni(II) complexes

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