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Issue 61, 2019
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High pressure synthesis of a quasi-one-dimensional GdFeO3-type perovskite PrCuO3 with nearly divalent Cu ions

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Abstract

A new perovskite-type cuprate PrCuO3 has been synthesized by high-pressure oxygen annealing. Synchrotron X-ray powder diffraction and absorption spectroscopy revealed that PrCuO3 crystallizes in the GdFeO3-type structure with cooperative Jahn–Teller distortion, forming one-dimensional chains of corner-shared CuO4 plaquettes with nearly divalent Cu ions.

Graphical abstract: High pressure synthesis of a quasi-one-dimensional GdFeO3-type perovskite PrCuO3 with nearly divalent Cu ions

  • This article is part of the themed collection: Perovskites
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Article information


Submitted
18 Jun 2019
Accepted
02 Jul 2019
First published
02 Jul 2019

Chem. Commun., 2019,55, 8931-8934
Article type
Communication
Author version available

High pressure synthesis of a quasi-one-dimensional GdFeO3-type perovskite PrCuO3 with nearly divalent Cu ions

M. Ito, H. Takahashi, H. Sakai, H. Sagayama, Y. Yamasaki, Y. Yokoyama, H. Setoyama, H. Wadati, K. Takahashi, Y. Kusano and S. Ishiwata, Chem. Commun., 2019, 55, 8931
DOI: 10.1039/C9CC04656A

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