Issue 58, 2019

Solvent-dependent, rhodium catalysed rearrangement reactions of sulfur ylides

Abstract

Benzyl thioethers undergo rhodium(II) catalyzed sigmatropic rearrangement reactions with aryldiazoacetates. Depending on the solvent and the electronic properties of the sulfide, the intermediate ylide undergoes either [1,2]- or [2,3]-sigmatropic rearrangement reactions in high yields.

Graphical abstract: Solvent-dependent, rhodium catalysed rearrangement reactions of sulfur ylides

Supplementary files

Article information

Article type
Communication
Submitted
16 May 2019
Accepted
24 Jun 2019
First published
25 Jun 2019

Chem. Commun., 2019,55, 8410-8413

Solvent-dependent, rhodium catalysed rearrangement reactions of sulfur ylides

Z. Yang, Y. Guo and R. M. Koenigs, Chem. Commun., 2019, 55, 8410 DOI: 10.1039/C9CC03809D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements