Issue 63, 2019
From the journal:

Chemical Communications

PINO/NHPI-mediated selective oxidation of cycloalkenes to cycloalkenones via a photo-electrochemical method†

Hiroyuki Tateno, ORCID logo a   Yugo Miseki ORCID logo a  and  Kazuhiro Sayama ORCID logo *a  

* Corresponding authors

a Advanced Functional Material Team, Research Center for Photovoltaics (RCPV), National Institution of Advanced Industrial Science and Technology (AIST), Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki, Japan
E-mail: k.sayama@aist.go.jp

Abstract

The selective photo-electrochemical oxidation of cyclohexene to 2-cyclohexene-1-one was successfully performed with excellent Faraday efficiency (>99%) via indirect oxidation with a PINO/NHPI mediator and O2 on a BiVO4/WO3 photoanode under low applied bias.

Graphical abstract: PINO/NHPI-mediated selective oxidation of cycloalkenes to cycloalkenones via a photo-electrochemical method

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Article information

DOI
https://doi.org/10.1039/C9CC03540K
Article type
Communication
Submitted
08 May 2019
Accepted
08 Jul 2019
First published
08 Jul 2019

Chem. Commun., 2019,55, 9339-9342

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PINO/NHPI-mediated selective oxidation of cycloalkenes to cycloalkenones via a photo-electrochemical method

H. Tateno, Y. Miseki and K. Sayama, Chem. Commun., 2019, 55, 9339 DOI: 10.1039/C9CC03540K

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