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Issue 51, 2019
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Efficient modulation of photoluminescence by hydrogen bonding interactions between inorganic [MnBr4]2− anions and organic cations

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Abstract

The different hydrogen bond interactions in two organic–inorganic hybrid manganese halide compounds, namely [A]2[MnBr4] (A = N-butyl-N-methylpyrrolidinium ([P14]+) for (1) and N-butyl-N-methylpiperidinium ([PP14]+) for (2)), lead to distinct photoluminescence quantum yields (81% for 1; 55% for 2). Further applications of luminescent 1 are also developed.

Graphical abstract: Efficient modulation of photoluminescence by hydrogen bonding interactions between inorganic [MnBr4]2− anions and organic cations

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Publication details

The article was received on 18 Apr 2019, accepted on 23 May 2019 and first published on 24 May 2019


Article type: Communication
DOI: 10.1039/C9CC03038G
Chem. Commun., 2019,55, 7303-7306

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    Efficient modulation of photoluminescence by hydrogen bonding interactions between inorganic [MnBr4]2− anions and organic cations

    L. Gong, Q. Hu, F. Huang, Z. Zhang, N. Shen, B. Hu, Y. Song, Z. Wang, K. Du and X. Huang, Chem. Commun., 2019, 55, 7303
    DOI: 10.1039/C9CC03038G

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