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Issue 61, 2019
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A radical capture mechanism for immediate Csp2–H bond hydroxylation via a heterogeneous Cu–graphene catalyst

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Abstract

A radical capture mechanism via a synergistic heterogeneous Cu2O–rGO catalyst for Csp2–H bond immediate hydroxylation has been developed. This protocol suggests the involvement of a C-centered radical (˙C), generated through an O-centered radical (˙OH) initiated hydrogen atom transfer (HAT) process.

Graphical abstract: A radical capture mechanism for immediate Csp2–H bond hydroxylation via a heterogeneous Cu–graphene catalyst

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Supplementary files

Article information


Submitted
15 Apr 2019
Accepted
19 Jun 2019
First published
20 Jun 2019

Chem. Commun., 2019,55, 8915-8918
Article type
Communication

A radical capture mechanism for immediate Csp2–H bond hydroxylation via a heterogeneous Cu–graphene catalyst

W. Sun, L. Gao and G. Zheng, Chem. Commun., 2019, 55, 8915
DOI: 10.1039/C9CC02906K

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