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Issue 38, 2019
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Dual dynamic chirality generated in the assembly of three achiral rods through the three-fold twisting of a macrocycle

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Abstract

We demonstrated dynamic chirality based on assemblies of three achiral rods with a twisted macrocycle. The three-fold twisting of a macrocycle can lead to two different chiral forms with C2- or D3-symmetry. Through a transmission of chirality to each dynamic chiral form, a helical-sense preference was successfully induced.

Graphical abstract: Dual dynamic chirality generated in the assembly of three achiral rods through the three-fold twisting of a macrocycle

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Article information


Submitted
20 Mar 2019
Accepted
16 Apr 2019
First published
16 Apr 2019

Chem. Commun., 2019,55, 5503-5506
Article type
Communication

Dual dynamic chirality generated in the assembly of three achiral rods through the three-fold twisting of a macrocycle

R. Katoono, K. Sakamoto and T. Suzuki, Chem. Commun., 2019, 55, 5503
DOI: 10.1039/C9CC02226K

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