Issue 33, 2019
From the journal:

Chemical Communications

Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids†

Lun Jina  and  Michael A. Hayward ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, UK
E-mail: michael.hayward@chem.ox.,ac.uk

Abstract

The first rhodium-containing oxide-hydride phases, LaSrCo0.5Rh0.5O3H and La0.5Sr1.5Mn0.5Rh0.5O3H, have been prepared via topochemical anion exchange. This clearly demonstrates the ability of rhodium, a late 4d transition metal, to kinetically stabilize oxide-hydride lattices, reinforcing the paradigm of covalent stabilization of transition-metal oxide-hydride phases.

Graphical abstract: Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids

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Article information

DOI
https://doi.org/10.1039/C9CC01768B
Article type
Communication
Submitted
04 Mar 2019
Accepted
01 Apr 2019
First published
01 Apr 2019

Chem. Commun., 2019,55, 4861-4864

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Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids

L. Jin and M. A. Hayward, Chem. Commun., 2019, 55, 4861 DOI: 10.1039/C9CC01768B

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