Issue 31, 2019
From the journal:

Chemical Communications

A Pd-catalyzed ring opening coupling reaction of 2,3-allenylic carbonates with cyclopropanols†

Jie Lin,a   Tonghao Zhu,a   Minqiang Jiaa  and  Shengming Ma ORCID logo *ab  

* Corresponding authors

a Research Center for Molecular Recognition and Synthesis, Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, P. R. China

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, P. R. China
E-mail: masm@sioc.ac.cn
Fax: +86 21-64167510

Abstract

A palladium-catalyzed coupling reaction of 2,3-allenylic carbonates with cyclopropanols was developed, affording valuable 1,3-diene products with different functional groups efficiently under mild reaction conditions. Gram scale synthesis was easily conducted with synthetic transformations demonstrated.

Graphical abstract: A Pd-catalyzed ring opening coupling reaction of 2,3-allenylic carbonates with cyclopropanols

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Article information

DOI
https://doi.org/10.1039/C9CC00979E
Article type
Communication
Submitted
02 Feb 2019
Accepted
20 Mar 2019
First published
21 Mar 2019

Chem. Commun., 2019,55, 4523-4526

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A Pd-catalyzed ring opening coupling reaction of 2,3-allenylic carbonates with cyclopropanols

J. Lin, T. Zhu, M. Jia and S. Ma, Chem. Commun., 2019, 55, 4523 DOI: 10.1039/C9CC00979E

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