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Issue 32, 2019
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The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

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Abstract

A post-synthesis thermal treatment of metastable phases in the high-pressure stabilised perovskite BiFe1−yScyO3 system results in the irreversible formation of polymorphs which represent novel polar and antipolar structures with interesting magnetic properties. Such annealing-stimulated polymorphism is believed to be a general phenomenon which can be found in other systems.

Graphical abstract: The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

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Publication details

The article was received on 18 Jan 2019, accepted on 25 Mar 2019 and first published on 26 Mar 2019


Article type: Communication
DOI: 10.1039/C9CC00472F
Chem. Commun., 2019,55, 4683-4686

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    The phenomenon of conversion polymorphism in Bi-containing metastable perovskites

    D. D. Khalyavin, A. N. Salak, E. L. Fertman, O. V. Kotlyar, E. Eardley, N. M. Olekhnovich, A. V. Pushkarev, Y. V. Radyush, A. V. Fedorchenko, V. A. Desnenko, P. Manuel, L. Ding, E. Čižmár and A. Feher, Chem. Commun., 2019, 55, 4683
    DOI: 10.1039/C9CC00472F

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