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Issue 22, 2019
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Facile and reversible double dearomatization of pyridines in non-phosphine MnI complexes with N,S-donor pyridinophane ligand

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Abstract

Single and double dearomatization of pyridine rings was observed in MnI complexes with an N2S2 pyridinophane ligand via deprotonation of one or two CH2 arms, respectively. In contrast to other N,S-donor pincer-like systems, the dearomatized (N2S2)Mn species were found to be stable, with the dearomatization being reversible.

Graphical abstract: Facile and reversible double dearomatization of pyridines in non-phosphine MnI complexes with N,S-donor pyridinophane ligand

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Submitted
17 Jan 2019
Accepted
21 Feb 2019
First published
21 Feb 2019

Chem. Commun., 2019,55, 3282-3285
Article type
Communication

Facile and reversible double dearomatization of pyridines in non-phosphine MnI complexes with N,S-donor pyridinophane ligand

A. Sarbajna, P. H. Patil, M. H. Dinh, O. Gladkovskaya, R. R. Fayzullin, S. Lapointe, E. Khaskin and J. R. Khusnutdinova, Chem. Commun., 2019, 55, 3282
DOI: 10.1039/C9CC00424F

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