Issue 24, 2019
From the journal:

Chemical Communications

Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds†

Chao Yan,abc   Xiujuan Qi,b   Kangcai Wang,a   Yunhe Jin,a   Guangbin Cheng, ORCID logo *c   Tianlin Liu,a   Hongwei Yang ORCID logo c  and  Qinghua Zhang ORCID logo *ac  

* Corresponding authors

a Institute of Chemical Materials, China Academy of Engineering Physics (CAEP), Mianyang, China
E-mail: qinghuazhang@caep.cn

b School of Material Science and Engineering, Sichuan Co-Innovation Center for New Energetic Materials, Southwest University of Science and Technology, Mianyang, P. R. China

c School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, China
E-mail: gcheng@mail.njust.edu.cn

Abstract

A novel fused-ring polynitro compound (5) and a cyclic compound featuring gem-dinitromethylene and nitroso groups (7) were synthesized from 1,1-diamino-2,2-dinitroethylene (FOX-7). Both compounds exhibit high density, decent thermal stability, high detonation performances, and low mechanical sensitivities. This newly developed derivatization strategy enriches the ever-expanding reactive chemistry of FOX-7.

Graphical abstract: Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds

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Article information

DOI
https://doi.org/10.1039/C8CC10178G
Article type
Communication
Submitted
24 Dec 2018
Accepted
25 Feb 2019
First published
26 Feb 2019

Chem. Commun., 2019,55, 3497-3500

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Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds

C. Yan, X. Qi, K. Wang, Y. Jin, G. Cheng, T. Liu, H. Yang and Q. Zhang, Chem. Commun., 2019, 55, 3497 DOI: 10.1039/C8CC10178G

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