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Issue 11, 2019
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Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands

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Abstract

While P(V) 1,2-oxaphosphetanes were investigated in great detail over the past decades, the knowledge about P(V) 1,2-thiaphosphetanes is rather scarce, and P(III) derivatives are unknown. Herein, we present the synthesis of the first P(III) complex derivatives formed in the coordination sphere of group 6 metals and, additionally, the first unligated P(III) 1,2-thiaphosphetanes. The latter display an unusually low HOMO–LUMO gap thus constituting excellent candidates for redox-cycling organocatalysts.

Graphical abstract: Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands

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Submitted
13 Dec 2018
Accepted
08 Jan 2019
First published
18 Jan 2019

Chem. Commun., 2019,55, 1615-1618
Article type
Communication

Synthesis of free and ligated 1,2-thiaphosphetanes – expanding the pool of strained P-ligands

A. W. Kyri, F. Gleim, D. Becker, G. Schnakenburg, A. Espinosa Ferao and R. Streubel, Chem. Commun., 2019, 55, 1615
DOI: 10.1039/C8CC09892A

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