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Issue 12, 2019
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Hollow core–shell ZnO@ZIF-8 on carbon cloth for flexible supercapacitors with ultrahigh areal capacitance

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Abstract

Rational design and synthesis of hollow core–shell hetero-structures with high complexity still remains challenging for high-performance supercapacitors. Here, a simple and effective strategy that involves a ‘root-etch-wrap’ process was developed to synthesize hollow core–shell hetero-structured electrodes. Specifically, ZnO hollow spheres take root on carbon cloth via an in situ growth routine, then are etched to aid the generation of a ZIF-8 shell. As-synthesized hollow core–shell ZnO@ZIF-8 is wrapped by PANI nanocoating, resulting in a flexible conductive porous electrode (denoted as PANI/ZnO@ZIF-8-CC). The optimized electrode exhibits an ultrahigh areal capacitance (4839–3987 mF cm−2 at 5–30 mA cm−2), which is at least 3 times higher than that of PANI-CC and ZnO@ZIF-8-CC owing to the synergistic effect. In addition, a symmetric flexible supercapacitor fabricated by PANI/ZnO@ZIF-8-CC exhibits a high energy density of 0.137–0.0891 mW h cm−3 (at a power density of 1.421–23.629 W cm−3) and a good long-term cycling ability (87% for 10 000 cycles at 5 mA cm−2). All of these results make unique core–shell structured PANI/ZnO@ZIF-8-CC a promising electrode material for advanced energy storage and conversion applications.

Graphical abstract: Hollow core–shell ZnO@ZIF-8 on carbon cloth for flexible supercapacitors with ultrahigh areal capacitance

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Publication details

The article was received on 13 Dec 2018, accepted on 14 Jan 2019 and first published on 14 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC09847F
Citation: Chem. Commun., 2019,55, 1746-1749

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    Hollow core–shell ZnO@ZIF-8 on carbon cloth for flexible supercapacitors with ultrahigh areal capacitance

    X. Cao and Z. Han, Chem. Commun., 2019, 55, 1746
    DOI: 10.1039/C8CC09847F

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