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Issue 25, 2019
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Controlling the crystalline structure of imine-linked 3D covalent organic frameworks

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Abstract

We explore the growth mechanism of 3D Covalent Organic Frameworks (COFs) using imine-linked model systems. We confirm that 3D imine COFs crystalize through an amorphous polymer intermediate, whose conditional state is key for preferential generation of the ideal porous structure over the collapsed hydrated form.

Graphical abstract: Controlling the crystalline structure of imine-linked 3D covalent organic frameworks

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Article information


Submitted
01 Dec 2018
Accepted
22 Feb 2019
First published
28 Feb 2019

This article is Open Access

Chem. Commun., 2019,55, 3594-3597
Article type
Communication

Controlling the crystalline structure of imine-linked 3D covalent organic frameworks

D. M. Fischbach, G. Rhoades, C. Espy, F. Goldberg and B. J. Smith, Chem. Commun., 2019, 55, 3594
DOI: 10.1039/C8CC09571J

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