Issue 7, 2019
From the journal:

Chemical Communications

Stepwise degradation of hydroxyl compounds to aldehydes via successive C–C bond cleavage†

Mingyang Liu,ab   Zhanrong Zhang,*a   Xiaojun Shen, ORCID logo ab   Huizhen Liu, ORCID logo a   Pei Zhang,a   Bingfeng Chen ORCID logo b  and  Buxing Han ORCID logo *ab  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Key Laboratory of Colloid and Interface and Thermodynamics, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun North First Street 2, 100190 Beijing, P. R. China
E-mail: zhangzhanrong@iccas.ac.cn, hanbx@iccas.ac.cn

b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

Stepwise degradation of hydroxyl compounds to aldehydes via successive cleavage of C–C bonds was achieved by using a bimetallic catalytic system (PdCl2 + CuCl) without any ligands and additives. The broad applicability is expanded to a diverse range of aromatic, aliphatic, primary and secondary alcohols, as well as lignin model compounds.

Graphical abstract: Stepwise degradation of hydroxyl compounds to aldehydes via successive C–C bond cleavage

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Article information

DOI
https://doi.org/10.1039/C8CC09504C
Article type
Communication
Submitted
29 Nov 2018
Accepted
19 Dec 2018
First published
19 Dec 2018

Chem. Commun., 2019,55, 925-928

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Stepwise degradation of hydroxyl compounds to aldehydes via successive C–C bond cleavage

M. Liu, Z. Zhang, X. Shen, H. Liu, P. Zhang, B. Chen and B. Han, Chem. Commun., 2019, 55, 925 DOI: 10.1039/C8CC09504C

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