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Issue 5, 2019
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A mono-metallic Pd(II)-cage featuring two different polar binding sites

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Abstract

The tetra-α isomer of a super aryl-extended tetra-pyridyl calix[4]pyrrole self-assembles into a mono-metallic Pd(II)-cage featuring two different and converging polar binding sites. Mono- and di-topic polar guests are bound reversibly in the cage. A mechanism for guest exchange in the cage complexes is proposed.

Graphical abstract: A mono-metallic Pd(ii)-cage featuring two different polar binding sites

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Publication details

The article was received on 19 Nov 2018, accepted on 11 Dec 2018 and first published on 12 Dec 2018


Article type: Communication
DOI: 10.1039/C8CC09195A
Chem. Commun., 2019,55, 604-607

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    A mono-metallic Pd(II)-cage featuring two different polar binding sites

    L. Escobar, D. Villarón, E. C. Escudero-Adán and P. Ballester, Chem. Commun., 2019, 55, 604
    DOI: 10.1039/C8CC09195A

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