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Issue 10, 2019
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Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

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Abstract

We report herein that the mode of entanglement in square lattice, sql, coordination networks formed by an extended bis-imidazole ligand, L, can be controlled by the solvent used during solvothermal synthesis. [ML2(NO3)2]n (M = Co, Ni) exhibit both parallel 2D → 2D interpenetration and, unusually, mixed entanglement (parallel–inclined 2D → 3D polycatenation).

Graphical abstract: Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

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Publication details

The article was received on 17 Nov 2018, accepted on 09 Jan 2019 and first published on 09 Jan 2019


Article type: Communication
DOI: 10.1039/C8CC09152H
Chem. Commun., 2019,55, 1454-1457

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    Solvent-directed control over the topology of entanglement in square lattice (sql) coordination networks

    R. Sanii, C. Hua, E. Patyk-Kaźmierczak and M. J. Zaworotko, Chem. Commun., 2019, 55, 1454
    DOI: 10.1039/C8CC09152H

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