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Issue 14, 2019
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Rhodium(iii)-catalyzed sulfonamide directed ortho C–H carbenoid functionalization via metal carbene migratory insertion

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Abstract

A rhodium(III)-catalyzed sulfonamide directed ortho C–H carbenoid functionalization has been developed with good yields. This method is attractive due to its broad substrate scope, and enables derivation of diverse biologically active sulfonamide structures and late-stage modification of sulfa drugs.

Graphical abstract: Rhodium(iii)-catalyzed sulfonamide directed ortho C–H carbenoid functionalization via metal carbene migratory insertion

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Supplementary files

Article information


Submitted
06 Nov 2018
Accepted
05 Dec 2018
First published
06 Dec 2018

Chem. Commun., 2019,55, 2027-2030
Article type
Communication

Rhodium(III)-catalyzed sulfonamide directed ortho C–H carbenoid functionalization via metal carbene migratory insertion

Y. Dong, J. Chen and H. Xu, Chem. Commun., 2019, 55, 2027
DOI: 10.1039/C8CC08837C

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