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Issue 8, 2019
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Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage

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Abstract

Partial dehydrobromination of a diprotic pincer-type ruthenium complex in the presence of a rigid 1,3-bis(diphenylphosphino)benzene linker provided a dinuclear cage containing a guest template KBr surrounded by hydrogen bonds and electrostatic interactions. Dinitrogen and carbon disulfide were encapsulated into the cage with proton channels formed by the pyrazole arms in the pincer ligands.

Graphical abstract: Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage

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Article information


Submitted
19 Oct 2018
Accepted
30 Nov 2018
First published
30 Nov 2018

Chem. Commun., 2019,55, 1028-1031
Article type
Communication
Author version available

Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage

T. Toda, S. Suzuki and S. Kuwata, Chem. Commun., 2019, 55, 1028
DOI: 10.1039/C8CC08384C

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