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Issue 4, 2019
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Visible-light mediated carbamoyl radical addition to heteroarenes

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Abstract

The generation of carbamoyl radicals, followed by their addition to heteroarenes, was performed under mild conditions through a metal-free photocatalyzed decarboxylation of oxamic acids. The process has been applied to the carbamoylation of heteroaromatic bases using α-aminoacid-derived oxamic acids, leading to the corresponding amides without racemization.

Graphical abstract: Visible-light mediated carbamoyl radical addition to heteroarenes

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Article information


Submitted
17 Oct 2018
Accepted
05 Dec 2018
First published
06 Dec 2018

Chem. Commun., 2019,55, 466-469
Article type
Communication

Visible-light mediated carbamoyl radical addition to heteroarenes

A. H. Jatoi, G. G. Pawar, F. Robert and Y. Landais, Chem. Commun., 2019, 55, 466
DOI: 10.1039/C8CC08326F

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