Photochemical reactions of triplet phenylphosphinidene with carbon monoxide and nitric oxide

Abstract

Here we report the photochemical reactions of triplet phenylphosphinidene with carbon monoxide and nitric oxide. The photolysis of phenylphosphirane in carbon monoxide-doped matrices enabled the first spectroscopic identification of phenylphosphaketene, the hitherto unreported phosphorus analogue of phenyl isocyanate. The hitherto undisclosed phosphinimine-N-oxyl radical formed upon UV irradiation of the phenylphosphinidene with nitric oxide in argon matrices at 10 K.