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Issue 97, 2018
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Photochemical reactions of triplet phenylphosphinidene with carbon monoxide and nitric oxide

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Abstract

Here we report the photochemical reactions of triplet phenylphosphinidene with carbon monoxide and nitric oxide. The photolysis of phenylphosphirane in carbon monoxide-doped matrices enabled the first spectroscopic identification of phenylphosphaketene, the hitherto unreported phosphorus analogue of phenyl isocyanate. The hitherto undisclosed phosphinimine-N-oxyl radical formed upon UV irradiation of the phenylphosphinidene with nitric oxide in argon matrices at 10 K.

Graphical abstract: Photochemical reactions of triplet phenylphosphinidene with carbon monoxide and nitric oxide

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Supplementary files

Article information


Submitted
30 Oct 2018
Accepted
12 Nov 2018
First published
12 Nov 2018

Chem. Commun., 2018,54, 13694-13697
Article type
Communication

Photochemical reactions of triplet phenylphosphinidene with carbon monoxide and nitric oxide

A. Mardyukov and D. Niedek, Chem. Commun., 2018, 54, 13694
DOI: 10.1039/C8CC08664H

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