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Issue 98, 2018
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Hydride transfer initiated ring expansion of pyrrolidines toward highly functionalized tetrahydro-1-benzazepines

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Abstract

A novel hydride transfer initiated ring expansion of 4-pyrrolidinyl isatins to synthesize tetrahydro-1-benzazepines has been developed. This methodology represents an atom- and step-economical protocol to assemble seven-membered polycyclic amines from pyrrolidine derivatives in one step.

Graphical abstract: Hydride transfer initiated ring expansion of pyrrolidines toward highly functionalized tetrahydro-1-benzazepines

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Publication details

The article was received on 15 Oct 2018, accepted on 14 Nov 2018 and first published on 14 Nov 2018


Article type: Communication
DOI: 10.1039/C8CC08238C
Citation: Chem. Commun., 2018,54, 13833-13836

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    Hydride transfer initiated ring expansion of pyrrolidines toward highly functionalized tetrahydro-1-benzazepines

    S. Wang, X. An, S. Li, X. Liu, Q. Liu and J. Xiao, Chem. Commun., 2018, 54, 13833
    DOI: 10.1039/C8CC08238C

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