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Issue 84, 2018
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Rhodium(III)-catalysed decarbonylative annulation through C–H activation: expedient access to aminoisocoumarins by weak coordination

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Abstract

Rhodium-catalysed decarbonylative annulation of isatoic anhydrides with alkynes through C–H activation for the synthesis of aminoisocoumarins was developed. This enables the gram-scale transformation to iodoisocoumarin which is a vital building block in transition-metal-catalysed cross couplings. These compounds exhibit blue-emitting luminescence properties.

Graphical abstract: Rhodium(iii)-catalysed decarbonylative annulation through C–H activation: expedient access to aminoisocoumarins by weak coordination

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Publication details

The article was received on 04 Sep 2018, accepted on 14 Sep 2018 and first published on 18 Sep 2018


Article type: Communication
DOI: 10.1039/C8CC07167E
Citation: Chem. Commun., 2018,54, 11889-11892

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    Rhodium(III)-catalysed decarbonylative annulation through C–H activation: expedient access to aminoisocoumarins by weak coordination

    S. Mayakrishnan, Y. Arun, N. Uma Maheswari and P. T. Perumal, Chem. Commun., 2018, 54, 11889
    DOI: 10.1039/C8CC07167E

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