Issue 91, 2018

A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition

Abstract

An exceedingly rare three-dimensional CO2-coordinated inorganic polyoxoanion was prepared by a hydrothermal synthesis reaction. The CO2 ligand connects with two Zn-ε-Keggin cores in a linear and symmetrical μ22o,o coordination pattern with a C[double bond, length as m-dash]O bond length of 1.099(112) Å. The new compound reported here exhibits not only appealing structures but also high catalytic activity for the cycloaddition of carbon dioxide with epoxides.

Graphical abstract: A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition

Supplementary files

Article information

Article type
Communication
Submitted
30 Aug 2018
Accepted
26 Sep 2018
First published
26 Sep 2018

Chem. Commun., 2018,54, 12808-12811

A rare three-dimensional POM-based inorganic metal polymer bonded by CO2 with high catalytic performance for CO2 cycloaddition

W. Cheng, Y. Xue, X. Luo and Y. Xu, Chem. Commun., 2018, 54, 12808 DOI: 10.1039/C8CC07041E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements