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Issue 80, 2018
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A semiconducting metal-chalcogenide–organic framework with square-planar tetra-coordinated sulfur

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Abstract

We demonstrated here a novel semiconducting metal-chalcogenide–organic framework (MCOF-89) with an optical bandgap through the unlikely assembly between a metal chalcogenide unit and carboxylic acid. The elusive metal-chalcogenide unit [Mn44-S)] with square-planar tetra-coordinated sulfur (sptS) is for the first time observed in MOFs.

Graphical abstract: A semiconducting metal-chalcogenide–organic framework with square-planar tetra-coordinated sulfur

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Article information


Submitted
29 Aug 2018
Accepted
13 Sep 2018
First published
20 Sep 2018

Chem. Commun., 2018,54, 11272-11275
Article type
Communication

A semiconducting metal-chalcogenide–organic framework with square-planar tetra-coordinated sulfur

H. Yang, M. Luo, Z. Wu, W. Wang, C. Xue and T. Wu, Chem. Commun., 2018, 54, 11272
DOI: 10.1039/C8CC06997B

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