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Issue 81, 2018
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Exogenous-oxidant-free electrochemical oxidative C–H sulfonylation of arenes/heteroarenes with hydrogen evolution

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Abstract

An efficient and environmentally benign electrochemical oxidative radical C–H sulfonylation of arenes/heteroarenes was developed in this work. A series of significant diarylsulfones were prepared under mild catalyst- and exogenous-oxidant-free reaction conditions, which efficiently avoid the issues of desulfonylation or over-reduction of sulfonyl groups.

Graphical abstract: Exogenous-oxidant-free electrochemical oxidative C–H sulfonylation of arenes/heteroarenes with hydrogen evolution

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Article information


Submitted
08 Aug 2018
Accepted
07 Sep 2018
First published
26 Sep 2018

Chem. Commun., 2018,54, 11471-11474
Article type
Communication

Exogenous-oxidant-free electrochemical oxidative C–H sulfonylation of arenes/heteroarenes with hydrogen evolution

Y. Yuan, Y. Yu, J. Qiao, P. Liu, B. Yu, W. Zhang, H. Liu, M. He, Z. Huang and A. Lei, Chem. Commun., 2018, 54, 11471
DOI: 10.1039/C8CC06451B

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