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Issue 85, 2018
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Synthesis and thermo-responsive behavior of helical polyacetylenes derived from proline

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Abstract

A series of optically active helical poly[(S)-2-ethynyl-N-aliphatic acylpyrrolidine] were efficiently synthesized from a commercially available biomass-based starting material, and that bearing a short propionyl substituent exhibited an unexpected lower critical solution temperature in an aqueous solution with a narrow phase-transition window and a small hysteresis.

Graphical abstract: Synthesis and thermo-responsive behavior of helical polyacetylenes derived from proline

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Article information


Submitted
18 Jul 2018
Accepted
25 Sep 2018
First published
25 Sep 2018

Chem. Commun., 2018,54, 12081-12084
Article type
Communication

Synthesis and thermo-responsive behavior of helical polyacetylenes derived from proline

G. Shi, S. Wang, X. Guan, J. Zhang and X. Wan, Chem. Commun., 2018, 54, 12081
DOI: 10.1039/C8CC05856C

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