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Issue 75, 2018
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Palladium-catalyzed sequential three-component reactions to access vinylsilanes

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Abstract

A palladium-catalyzed sequential three-component reaction has been developed. The palladacycles, generated through cascade reactions of aryl halides and alkynes, are the key intermediates and react with hexamethyldisilane to form disilylated products. The reaction represents a useful preparative method for vinylsilanes, and the vinylsilanes can be transformed into tetrasubstituted alkenes.

Graphical abstract: Palladium-catalyzed sequential three-component reactions to access vinylsilanes

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Publication details

The article was received on 30 Jun 2018, accepted on 27 Aug 2018 and first published on 28 Aug 2018


Article type: Communication
DOI: 10.1039/C8CC05254A
Chem. Commun., 2018,54, 10598-10601

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    Palladium-catalyzed sequential three-component reactions to access vinylsilanes

    B. Zhou, A. Lu, C. Shao, X. Liang and Y. Zhang, Chem. Commun., 2018, 54, 10598
    DOI: 10.1039/C8CC05254A

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